Minggu, 11 Oktober 2009

Standard State Conditions - Standard Temperature and Pressure

Values of thermodynamic quantities are commonly expressed for standard state conditions, so it is a good idea to understand what the standard state conditions are.

A superscript circle is used to denote a thermodynamic quantity that is under standard state conditions:

ΔH = ΔH°
ΔS = ΔS°
ΔS = ΔS°

Standard State Conditions

Certain assumptions apply to standard state conditions. Standard temperature and pressure commonly is abbreviated as STP.
  • The standard state temperature is 25°C (298 K). It is possible to calculate standard state values for other temperatures.

  • All liquids are pure.

  • The concentration of all solutions is 1 M (1 molar).

  • All gases are pure.

  • All gases are at 1 atm pressure.

  • The energy of formation of an element in its normal state is defined as zero.

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